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Adhesives & Sealants
Evonik Operations GmbH, BL Silanes
Hydrophobic Dynasylan® 1146 diaminofunctional silane is used in adhesives and sealants, and in coatings, to improve the adhesion of amino-reactive resins (e.g. RTV-silicones, two-part urethanes, silylated urethanes, MS polymers, and two-part epoxies) to inorganic surfaces, plastic surfaces, and inorganic fillers. Dynasylan® 1146 silane is characterized by randomly distributed linear and cyclic oligosiloxanes and it fulfills the OECD polymer definition. Its low volatility and viscosity make compounding easy. Dynasylan® 1146 silane produces significantly less by-product (VOC) and has a correspondingly low odor level during application.
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Dynasylan® 1124 is a secondary aminofunctional methoxy-silane. The product acts as an adhesion promoter between inorganic materials (for example glass, metals and fillers) and organic polymers (thermosets, thermoplastics and elastomers). It can also be used for the chemical modification of polymers and isocyanates.
Dynasylan® 40 is a ethyl silicate with a silicon dioxide content of approximately 40 - 42 % upon complete hydrolysis (the Si content of Dynasylan® 40 is calculated as SiO2). Dynasylan® 40 is formed in the presence of water from tetraethyl silicate (Si[OEt]4) by partial hydrolysis of the ethoxy groups to hydroxyl groups and subsequent condensation with formation of siloxane bonds (-Si-O-Si-). Dynasylan® 40 is a colorless, low-viscosity liquid with an SiO2 content of 40% (the Si content of Dynasylan® 40 is calculated as SiO2). The polysilicic acids still have a sufficient content of ethoxy groups which can be activated by acid- or base-catalyzed hydrolysis. Condensation starts even during hydrolysis, with the formation of relatively large polymeric molecules. During storage of these hydrolysates, condensation continues until a gel is formed, where the rate depends on the degree of hydrolysis. The action of the hydrolysates as binders is based on the continuation of the hydrolysis with subsequent gelation and dehydration to give polymeric SiO2 structures.
Dynasylan® 4148 is a ready-to-use silane, soluble in water and most organic solvents. Dynasylan® 4148 is a rheological additive which reduces the viscosity of highly-filled polymer systems, like aluminum trihydroxide-filled polyesters or SMC-pastes. Contrary to most other organofunctional silanes, Dynasylan® 4148 features chemical polarity but has a non-reactive polar group. Furthermore, Dynasylan® 4148 can be used as anti-settling agent for fillers and pigments in paints as well as corrosion inhibitors in glycol based cooling agents.
Dynasylan® 6490 is a vinyl silane concentrate (oligomeric siloxane) containing vinyl and methoxy groups. Dynasylan® 6490 is a colourless, nearly odorless low-viscosity liquid. Dynasylan® 6490 is an excellent compatibiliser between inorganic fillers (e.g. kaolin, MDH, ATH) and organic polymers (e.g. EPDM, EVA, PE). The high boiling point of Dynasylan® 6490, together with its high flash point, gives it outstanding advantages with respect to safety and handling during processing. From an environmental viewpoint it should be noted that the amount of released hydrolysis methanol (VOC) is significantly reduced compared to monomeric vinyl silanes.